| Hermetic motor burnout; charge recovered, system open | Both | Acidity and chloride on the refrigerant decide whether the recovered charge is worth reclaiming or is scrap. The oil tells you whether the clean-up is finished before you recharge — which is a different question, asked of a different sample, and one the refrigerant result cannot answer. |
| Reclaimed batch about to be sold on | Refrigerant | This is the case AHRI 700 exists for, and the one where the laboratory behind the number becomes part of your record rather than a formality. The limits are published here. |
| Cylinder of unknown provenance, or a label you do not trust | Refrigerant | Composition, not purity, is what catches this. A blend can be 99.5% pure and still fail, because each component has its own two-sided window. A single purity figure will pass material that is out of specification. |
| Scheduled chiller PM, machine running normally | Oil | Oil is the one that repays a routine interval, because it is a trend. Add a refrigerant test when the machine has been opened, topped up from a cylinder you did not fill yourself, or run on a charge of unknown history. |
| Purge unit running more than it used to on a low-pressure machine | Neither | AHRI 700 exempts fluids whose normal boiling point is at or above room temperature from the non-condensables characteristic — R-11, R-113, R-123, R-141b, R-245fa, R-1233zd(E). A 700 result on your R-123 charge therefore will not report the air your purge unit is pulling; that is a machine measurement, and no laboratory result substitutes for it. Test the charge if its moisture, acidity or oil carry-over is in question — just not for this. |
| Acid or burnt smell at the service valve | Both | Acidity limits are per fluid — 1 and 3 ppm as HCl across the published table — and chloride is its own check: Turbidity — turbidity appears at roughly 3 ppm by weight. The oil holds what the charge left behind, so the two samples answer different halves of the same question. |
| Moisture suspicion — drier indicator, sight glass, system opened | Both | Water limits are 10 / 15 / 20 / 100 ppm depending on the fluid, not one number, and a generic limit column will judge a low-pressure charge against the wrong one. On the oil side, moisture is the number the sampling procedure is built around — the bottle is degassed before it is sealed and the sample goes out promptly, because a sample that waits measures the wait. |